首页> 外文OA文献 >Thermodynamic Properties of Mixtures Containing Ionic Liquids. 4. LLE of Binary Mixtures of [C2MIM][NTf2] with Propan-1-ol, Butan-1-ol, and Pentan-1-ol and [C4MIM][NTf2] with Cyclohexanol and 1,2-Hexanediol Including Studies of the Influence of Small Amounts of Water
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Thermodynamic Properties of Mixtures Containing Ionic Liquids. 4. LLE of Binary Mixtures of [C2MIM][NTf2] with Propan-1-ol, Butan-1-ol, and Pentan-1-ol and [C4MIM][NTf2] with Cyclohexanol and 1,2-Hexanediol Including Studies of the Influence of Small Amounts of Water

机译:含离子液体的混合物的热力学性质。 4. [C2MIM] [NTf2]与丙-1-醇,Butan-1-ol和戊丹-1-醇以及[C4MIM] [NTf2]与环己醇和1,2-己二醇的二元混合物的LEE研究包括少量水的影响

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摘要

Experimental data are presented for liquid-liquid equilibria of mixtures of the room-temperature ionic liquid 1-ethyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide ([C2MIM][NTf2]) with the three alcohols propan-1-ol, butan-1-ol, and pentan-1-ol and for the 1-butyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl) imide ([C4MIM][NTf2]) with cyclohexanol and 1,2-hexanediol in the temperature range of 275 K to 345 K at ambient pressure. The synthetic method has been used. Cloud points at a given composition were observed by varying the temperature and using light scattering to detect the phase splitting. In addition, the influence of small amounts of water on the demixing temperatures of binary mixtures of [C2MIM][NTf2] and propan-1-ol, butan-1-ol, and pentan-1-ol was investigated.
机译:给出了室温离子液体1-乙基-3-甲基-咪唑双(三氟甲基磺酰基)酰亚胺([C2MIM] [NTf2])与三种醇propan-1-ol混合物的液-液平衡的实验数据。丁烷醇和戊烷醇和1-丁-3-甲基咪唑双(三氟甲基磺酰基)酰亚胺([C4MIM] [NTf2])与环己醇和1,2-己二醇的温度范围为在环境压力下为275 K至345K。已使用合成方法。通过改变温度并使用光散射检测相分裂,可以观察到给定成分下的浊点。另外,研究了少量水对[C2MIM] [NTf2]与丙-1-醇,丁-1-醇和戊丹-1-醇的二元混合物的分离温度的影响。

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